Back Up your Certificates on Plesk
Global Support Centre > SSL Certificates > Plesk > Back Up Certificates
Plesk stores the SSL related files in a httpd.pem file inside a "cert" folder. Both the RSA private key and Certificate are kept inside this file the path to which is: /home/httpd/vhosts/domain.com/cert/httpd.pem
Backup the the RSA private key from this folder.

